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Nitrogen laser
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Nitrogen laser : ウィキペディア英語版
Nitrogen laser

A nitrogen laser is a gas laser operating in the ultraviolet range〔C. S. Willett, ''Introduction to Gas Lasers: Population Inversion Mechanisms'' (Pergamon, New York,1974).〕 (typically 337.1 nm) using molecular nitrogen as its gain medium, pumped by an electrical discharge.
The wall-plug efficiency of the nitrogen laser is low, typically 0.1% or less, though nitrogen lasers with efficiency of up to 3% have been reported in the literature. The wall-plug efficiency is the product of the following three efficiencies:
* electrical: TEA laser
* gain medium: This is the same for all nitrogen lasers and thus has to be at least 3%
*
* inversion by electron impact is 10 to 1 due to Franck–Condon principle
*
* energy lost in the lower laser level: 40%
* optical: More induced emission than spontaneous emission
==Gain medium==
The gain medium is nitrogen molecules in the gas phase. The nitrogen laser is a three-level laser. In contrast to more typical four-level lasers, the upper laser level of nitrogen is directly pumped, imposing no speed limits on the pump. Pumping is normally provided by direct electron impact; the electrons must have sufficient energy, or they will fail to excite the upper laser level. Typically reported optimum values are in the range of 80 to 100 eV per Torr·cm pressure of nitrogen gas.
There is a 40 ns upper limit of laser lifetime at low pressures and the lifetime becomes shorter as the pressure increases. The lifetime is only 1 to 2 ns at 1 atmosphere. In general
:t () = \cfrac">)}.
The strongest lines are at 337.1 nm wavelength in the ultraviolet. Other lines have been reported at 357.6 nm, also ultraviolet. This information refers to the second positive system of molecular nitrogen, which is by far the most common. No vibration of the two nitrogen atoms is involved, because the atom-atom distance does not change with the electronic transition. The rotation needs to change to deliver the angular momentum of the photon, furthermore multiple rotational states are populated at room temperature. There are also lines in the far-red and infrared from the first positive system, and a visible blue laser line from the molecular nitrogen positive (1+) ion.
The metastable lower level lifetime is 40 μs, thus, the laser self-terminates, typically in less than 20 ns. This type of self-termination is sometimes referred to as "bottlenecking in the lower level". This is only a rule of thumb as is seen in many other lasers:
The helium–neon laser also has a bottleneck as one decay step needs the walls of the cavity and this laser typically runs in continuous mode.
Several organic dyes with upper level lifetimes of less than 10 ns have been used in continuous mode.
The Nd:YAG laser has an upper level lifetime of 230 µs, yet it also supports 100 ps pulses.
Repetition rates can range as high as a few kHz, provided adequate gas flow and cooling of the structure are provided. Cold nitrogen is a better medium than hot nitrogen, and this appears to be part of the reason that the pulse energy and power drop as the repetition rate increases to more than a few pulses per second. There are also, apparently, issues involving ions remaining in the laser channel.
Air, which is 78% nitrogen, can be used, but more than 0.5% oxygen poisons the laser.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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